Fil:DiffusionMicroMacro.gif

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DiffusionMicroMacro.gif(360 × 300 billedpunkter, filstørrelse: 402 KB, MIME-type: image/gif, gentaget, 60 rammer, 6,5 s)


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Beskrivelse

Beskrivelse
English: Diffusion from a microscopic and macroscopic point of view. Initially, there are solute molecules on the left side of a barrier (magenta line) and none on the right. The barrier is removed, and the solute diffuses to fill the whole container. Top: A single molecule moves around randomly. Middle: With more molecules, there is a clear trend where the solute fills the container more and more evenly. Bottom: With an enormous number of solute molecules, the randomness is gone: The solute appears to move smoothly and systematically from high-concentration areas to low-concentration areas, following Fick's laws. Image is made in Mathematica, source code below.
Dato
Kilde Eget arbejde
Forfatter Sbyrnes321

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Public domain Jeg, indehaveren af ophavsretten til dette værk, udgiver dette værk som offentlig ejendom. Dette gælder i hele verden.
I nogle lande er dette ikke juridisk muligt. I så fald:
Jeg giver enhver ret til at anvende dette værk til ethvert formål, uden nogen restriktioner, medmindre sådanne restriktioner er påkrævede ved lov.

<< Mathematica source code >>

(* Source code written in Mathematica 6.0, by Steve Byrnes, 2010.
I release this code into the public domain. Sorry it's messy...email me any questions. *)

(*Particle simulation*)
SeedRandom[1];
NumParticles = 70;
xMax = 0.7;
yMax = 0.2;
xStartMax = 0.5;
StepDist = 0.04;
InitParticleCoordinates = Table[{RandomReal[{0, xStartMax}], RandomReal[{0, yMax}]}, {i, 1, NumParticles}];
StayInBoxX[x_] := If[x < 0, -x, If[x > xMax, 2 xMax - x, x]];
StayInBoxY[y_] := If[y < 0, -y, If[y > yMax, 2 yMax - y, y]];
StayInBoxXY[xy_] := {StayInBoxX[xy[[1]]], StayInBoxY[xy[[2]]]};
StayInBarX[x_] := If[x < 0, -x, If[x > xStartMax, 2 xStartMax - x, x]];
StayInBarY[y_] := If[y < 0, -y, If[y > yMax, 2 yMax - y, y]];
StayInBarXY[xy_] := {StayInBarX[xy[[1]]], StayInBarY[xy[[2]]]};
MoveAStep[xy_] := StayInBoxXY[xy + {RandomReal[{-StepDist, StepDist}], RandomReal[{-StepDist, StepDist}]}];
MoveAStepBar[xy_] := StayInBarXY[xy + {RandomReal[{-StepDist, StepDist}], RandomReal[{-StepDist, StepDist}]}];
NextParticleCoordinates[ParticleCoords_] := MoveAStep /@ ParticleCoords;
NextParticleCoordinatesBar[ParticleCoords_] := MoveAStepBar /@ ParticleCoords;
NumFramesBarrier = 10;
NumFramesNoBarrier = 50;
NumFrames = NumFramesBarrier + NumFramesNoBarrier;
ParticleCoordinatesTable = Table[0, {i, 1, NumFrames}];
ParticleCoordinatesTable[[1]] = InitParticleCoordinates;
For[i = 2, i <= NumFrames, i++,
  If[i <= NumFramesBarrier,
   ParticleCoordinatesTable[[i]] = NextParticleCoordinatesBar[ParticleCoordinatesTable[[i - 1]]], 
   ParticleCoordinatesTable[[i]] = NextParticleCoordinates[ParticleCoordinatesTable[[i - 1]]]];];

(*Plot full particle simulation*)
makeplotbar[ParticleCoord_] := 
  ListPlot[{ParticleCoord, {{xStartMax, 0}, {xStartMax, yMax}}}, Frame -> True, Axes -> False,
   PlotRange -> {{0, xMax}, {0, yMax}}, Joined -> {False, True}, PlotStyle -> {PointSize[.03], Thick},
   AspectRatio -> yMax/xMax, FrameTicks -> None];

makeplot[ParticleCoord_] := 
 ListPlot[ParticleCoord, Frame -> True, Axes -> False, PlotRange -> {{0, xMax}, {0, yMax}}, Joined -> False, 
  PlotStyle -> PointSize[.03], AspectRatio -> yMax/xMax, FrameTicks -> None]

ParticlesPlots = 
  Join[Table[makeplotbar[ParticleCoordinatesTable[[i]]], {i, 1, NumFramesBarrier}], 
   Table[makeplot[ParticleCoordinatesTable[[i]]], {i, NumFramesBarrier + 1, NumFrames}]];

(*Plot just the first particle in the list...Actually the fifth particle looks better. *) 
FirstParticleTable = {#[[5]]} & /@ ParticleCoordinatesTable;

FirstParticlePlots = 
  Join[Table[makeplotbar[FirstParticleTable[[i]]], {i, 1, NumFramesBarrier}], 
   Table[makeplot[FirstParticleTable[[i]]], {i, NumFramesBarrier + 1, NumFrames}]];


(* Continuum solution *)

(* I can use the simple diffusion-on-an-infinite-line formula, as long as I correctly periodically replicate the
initial condition. Actually just computed nearest five replicas in each direction, that was a fine approximation. *)

(* k = diffusion coefficient, visually matched to simulation. *)
k = .0007; 
u[x_, t_] := If[t == 0, If[x <= xStartMax, 1, 0], 1/2 Sum[
     Erf[(x - (-xStartMax + 2 n xMax))/Sqrt[4 k t]] - Erf[(x - (xStartMax + 2 n xMax))/Sqrt[4 k t]], {n, -5, 5}]];

ContinuumPlots = Join[
   Table[Show[
     DensityPlot[1 - u[x, 0], {x, 0, xMax}, {y, 0, yMax}, 
      ColorFunctionScaling -> False, AspectRatio -> yMax/xMax, 
      FrameTicks -> None],
     ListPlot[{{xStartMax, 0}, {xStartMax, yMax}}, Joined -> True, 
      PlotStyle -> {Thick, Purple}]],
    {i, 1, NumFramesBarrier}],
   Table[
    DensityPlot[1 - u[x, tt], {x, 0, xMax}, {y, 0, yMax}, 
     ColorFunctionScaling -> False, AspectRatio -> yMax/xMax, 
     FrameTicks -> None],
    {tt, 1, NumFramesNoBarrier}]];

(*Combine and export *)

TogetherPlots = 
  Table[GraphicsGrid[{{FirstParticlePlots[[i]]}, {ParticlesPlots[[i]]}, {ContinuumPlots[[i]]}},
   Spacings -> Scaled[0.2]], {i, 1, NumFrames}];

Export["test.gif", Join[TogetherPlots, Table[Graphics[], {i, 1, 5}]], 
 "DisplayDurations" -> {10}, "AnimationRepititions" -> Infinity ]

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Dato/tidMiniaturebilledeDimensionerBrugerKommentar
nuværende7. mar. 2012, 15:41Miniature af versionen fra 7. mar. 2012, 15:41360 × 300 (402 KB)Dratini0Just removed the white last fram for aesthetic purposes, and prologed the display time of the last frame to mark the reatart of the animation.
25. mar. 2010, 21:37Miniature af versionen fra 25. mar. 2010, 21:37360 × 300 (402 KB)AiyizoOptimized animation, converted to 256 color mode
16. jan. 2010, 11:57Miniature af versionen fra 16. jan. 2010, 11:57360 × 300 (529 KB)Sbyrnes321sped up bottom panel to match better with middle panel
16. jan. 2010, 11:46Miniature af versionen fra 16. jan. 2010, 11:46360 × 300 (508 KB)Sbyrnes321{{Information |Description={{en|1=Diffusion from a microscopic and macroscopic point of view. Initially, there are solute molecules on the left side of a barrier (purple line) and none on the right. The barrier is removed, and the solute diffuses to fill

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